Controlled Synthesis of Uniform,Micrometer‐Sized Ruthenium‐Functionalized Poly(N‐Isopropylacrylamide) Gel Particles and their Application to the Catalysis of the Belousov–Zhabotinsky Reaction

Ruthenium‐functionalized poly(N‐isopropyl acrylamide)‐based chemically oscillating microgels with diameters between 1 and 6 µm are synthesized by a modified precipitation polymerization approach. It is found that the initial amount of N‐isopropyl acrylamide (NIPAAm) can significantly affect the final sizes of the microgels. 2.5 g of initial NIPAAm results in microgels with maximum average diameter of ≈6 ± 0.5 µm. Making use of their fluorescence due to their ruthenium contents and their larger sizes compared to microgels prepared using other traditional methods, the impact of changes in the NaBrO₃ concentrations on their microscopic behavior is studied using a combination of fluorescence microscopy and dynamic light scattering techniques. When increasing the concentration of NaBrO₃ in a solution, the microgels first experience a decrease in size followed by aggregation that leads to the loss of colloidal stability. Finally, the redox potential behavior and optical performance of the Belousov–Zhabotinsky reaction catalyzed by these microgels are studied by electrochemical and spectroscopic means.

     

微米级硫酸钙晶须的制备

为了制备分布均一、具有较好光滑性和长径比的微米结构二水硫酸钙(CaSO4.2H2O)晶须,在室温条件下,以CaCl2和(NH4)2SO4为主要原料,通过一步超声反应制备出具有比较理想结构的微米级二水硫酸钙晶须。研究发现,在硫酸钙晶须生成过程中无水乙醇的量起着非常重要的作用,过多、过少的无水乙醇都不利于生成目标产物。CTAB的量对于二水硫酸钙晶须的长径比大小具有较大的调控作用。当无水乙醇的量为20mL,CTAB的浓度为0.9mmol/L,超声时间为1h时可以制备较理想的目标产物。120℃热处理2h晶须变碎,结果与热重结果相一致。与一般的晶体制备不同的是陈化时间对硫酸钙晶须的长径比无影响。通过X射线粉末衍射和热重分析分别对产物的结构和热稳定性进行了表征。结合实验简单探讨了二水硫酸钙晶须生成的机理,从中发现了制备较高长径比的二水硫酸钙晶须的一些规律。     

扫描电化学显微镜直接电沉积法构建葡萄糖氧化酶微米点

利用自制的凹形电极在铂基底电极上直接构建了葡萄糖氧化酶微米点. 首先, 将电聚合和电化学刻蚀法相结合制备了凹形铂微米电极. 然后将此种电极作为参比及辅助电极, 基底铂电极作为工作电极, 利用葡萄糖氧化酶在合适的条件下(浓度、一定量Triton X-100存在、电极电位等)由于电极表面pH的降低可以在铂电极上电沉积这一特性, 将酶固定在铂基底电极上, 微修饰得到了具有活性的葡萄糖氧化酶微米点. 最终用扫描电子显微镜和扫描电化学显微镜对所得微米点进行了表征. 所得微米点直径约20 μm, 且具有催化活性. 该方法简便, 干扰因素较少.     

基于AMESim的制动钳动态所需液量检测仿真研究

制动钳所需液量检测是制动钳性能检测中十分重要的一部分,目前关于制动钳动态所需液量检测研究缺乏理论和仿真依据,无法结合实际检测实现制动钳故障诊断,针对这一问题,在研究主缸位移差值法动态所需液量检测系统数学模型的基础上搭建AMEsim仿真模型,对主缸活塞速度和钳体结构因素进行仿真分析,并通过实验验证模型的正确性。结果表明：主缸活塞速度对动态所需液量检测影响较小;回位弹簧刚度、制动间隙和摩擦块、橡胶密封圈硬度对动态所需液量曲线有不同程度的影响,可以根据曲线特征实现制动钳故障诊断。     

对2005年高考试题中关于螺旋测微计实验试题的解析与拓展

解析了2005年普通高等学校全国联考(理综卷)中考察螺旋测微计原理的实验填空题,并给出了3方面的拓展:不常见的游标卡尺、圆弧游标、具有游标的螺旋测微计.     

A MORPHOLOGICAL STUDY OF POLY（DIVINYLBENZENE-co-ACRYLIC ACID） IN CROSSLINKING PRECIPITATION POLYMERIZATION

Divinylbenzene-80 （DVB-80） and polar monomer acrylic acid （AA） having hydrogen bonding at a total monomer loading of 5 vol% were precipitated-copolymerized in a variety of organic solvents with 2,2＇-azobis（isobutyronitrile） （AIBN） as initiator. The experiments were investigated from a two-dimensional matrix, i.e., the actual crosslinking degree of DVB varying from 0 to 80% and the solvent composition varying from 0 to 100% of toluene mixture with acetonitrile, when the mixture of acetonitrile and toluene was used as the reaction solvent. Under various reaction conditions, six distinct morphologies including soluble polymers, swellable microgels, coagulum, irregular microparticles, and nano-/micrometer microspheres were formed and the structures of these polymer architectures were described. A morphological map was utilized to discuss the effects of both crosslinking degree of DVB and composition of solvent on the transitions between morphology domains. The results demonstrated that the microspheres are formed by an internal contraction due to the marginal solvency of the continuous phase and the crosslinking of the polymer network through the covalent bonding from DVB as well as the interchain hydrogen-bonding between the carboxylic acid units.     

Size effects on tensile and fatigue behaviour of polycrystalline metal foils at the micrometer scale

Tensile and fatigue properties of as-rolled and annealed polycrystalline Cu foils with different thicknesses at the micrometer scale were investigated. Uniaxial tensile testing results showed that with decreasing foil thickness the uniform elongation decreases for both as-rolled and annealed foils, whereas the yield strength and ultimate tensile strength increase for as-rolled foils, but decrease for the annealed foils. For both the as-rolled or annealed foils, bending fatigue resistance decreases with decreasing the foil thickness. Deformation and fatigue damage behaviour of the free-standing foils were characterised as a function of foil thickness. In addition, the fatigue strength of various small-scale Cu foils was compared to understand the physical mechanisms of size effects on mechanical properties of the metallic material at micrometer scales.     

一套新型基于物理放大原理的微小长度测量工具的设计

设计了一套利用圆盘放大和普通长度测量工具相结合的测量微小长度的工具,分别利用该设计装置和螺旋测微器对钢丝的直径和普通A4纸张的厚度进行了测量。结果显示了新设计的可行性、创新性和数据的高精度性、准确性。     

微机电系统微尺度间隙的脉冲击穿特性

利用微机电系统(MEMS)工艺制备了5~40 m间隙的金属铝薄膜电极,测取了不同间隙下施加纳秒方波脉冲时的击穿电压,得到击穿电压和平均场强随电极间隙的变化规律,研究了脉宽、极性对击穿电压的影响,结合击穿后微电极扫描电镜观察结果讨论了其击穿机理,并与相同试样在直流下的结果进行了对比。研究表明:击穿电压随微间隙距离的增大而增大,击穿场强则随着间隙的增大迅速减小;与直流同间隙的击穿电压相比,脉冲作用下的击穿电压并不像宏观尺度下那样高出很多;试样击穿机理应为流注理论。在脉冲作用下,阳极出现了分层熔化现象,由于作用时间很短,阳极表面并未出现类似于直流击穿时留下的坑洞;阴极则出现了溅射沉积现象,只是沉积物质相对较少。     

采用千分表测定金属线胀系数

介绍采用千分表代替光杠杆法测量金属线胀系数的实验方法,该方法简化了实验设备,减少了实验中的不稳定因素,且易于操作．